Lithium battery cell process technology
Lithium battery cell process technology
Lithium battery technology involves several key steps in manufacturing high-performance and reliable batteries. This process can be divided
into three main stages: electrode manufacturing, battery assembly, and formation and aging. The following is a detailed breakdown:
1.Electrode Manufacturing
a) Mixing (Slurry Preparation)
- Cathode: Mix active materials (such as LiFePO, NMC, LCO), conductive additives (carbon black), binders (PVDF), and solvents (NMP) into
a slurry.
-Anode: Mixed graphite/silicon-based material, conductive carbon, binder (CMC/SBR), and water/solvent.
-Key parameters: uniformity, viscosity, and solid content.
b) Coating
- The slurry is coated onto metal foils:
- Cathode: Aluminum foil.
- Anode: Copper foil.
- Methods: Slot-die coating, comma coating, or blade coating.
- Drying: Solvent evaporation in an oven to form a dry electrode film.
c) Calendering (Roll Pressing)
- The coated electrodes are compressed to improve density and adhesion.
- Target: Optimal porosity (~30-50%) for electrolyte penetration.
d) Slitting- Large rolls of electrodes are cut into narrower strips for cell assembly.
2.Cell Assembl
a) Stacking/Winding
- Prismatic/Pouch Cells: Electrodes and separators are stacked in layers.
- Cylindrical Cells: Electrodes and separator are wound into a jelly roll.
- Separator: Typically PP/PE ceramic-coated for thermal stability.
b) Tab Welding
- Current collectors (tabs) are welded (ultrasonic/laser) to electrodes.
c) Encasing
- Cylindrical (e.g., 18650): Steel/Aluminum casing.
- Pouch: Aluminum laminate packaging (vacuum-sealed).
- Prismatic: Metal casing with laser welding.
d) Electrolyte Filling
- Liquid electrolyte is injected under vacuum.
- Solid-State Batteries: Use solid electrolytes (under development).
e) Sealing
- Final sealing to prevent leakage and moisture ingress.
3.Formation & Aging
a) Formation
- First charge/discharge cycle to form the SEI (Solid Electrolyte Interface) on the anode.
- Purpose: Stabilizes the cell and improves cycle life.
b) Aging
- Cells rest for days/weeks to detect self-discharge or defects.
- Degassing: Removal of gas generated during formation (for pouch cells).
Grading & Testing
- Capacity, impedance, and voltage are tested.
- Cells are sorted into performance grades.
Key Process Challenges
1. Precision Control: Coating thickness, slurry uniformity.
2. Contamination: Moisture, metal particles degrade performance.
3. Yield & Cost: High material costs (e.g., NMP solvent recovery).
4. Safety: Dry room (humidity <1%) to prevent Li reaction with moisture.
Emerging Technologies
- Dry Electrode Coating (Tesla’s acquisition of Maxwell Tech): Binder-free, solvent-free process.
- Solid-State Batteries: Eliminates liquid electrolyte.
- High-Speed Laser Cutting: Improves electrode precision.
Conclusion
The manufacturing process of lithium batteries is very complex and requires strict control over materials, environment, and equipment. The
advancement of process technology (such as dry electrodes, solid-state) aims to improve energy density, reduce costs, and enhance safety.
Would you like details on a specific step (e.g., electrolyte formulation, laser welding)?
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